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Search   
MSDS  
:
 Hexachloropropene, 96%
CAS  
:
 1888-71-7
SYNONYMS  
:
 Perchloropropene; Hexachloropropylene; chlorinated propene.

Section 1 - Chemical Product and Company Identification
MSDS Name: Hexachloropropene, 96%
Catalog Numbers: AC120450000, AC120450050, AC120450500
Synonyms:
Perchloropropene; Hexachloropropylene; chlorinated propene.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
1888-71-7 Hexachloropropene 96 217-560-9

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless to pale yellow liquid.
Warning! Causes eye, skin, and respiratory tract irritation. Harmful if inhaled.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation. Lachrymator (substance which increases the flow of tears).
Skin: Causes skin irritation. May cause contact dermatitis.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver damage. HSDB says chloropropanes and chloropropenes cause contact dermatitis, headache, vertigo, tearing, irritation of mucous membranes, and when ingested, liver damage in humans.
Inhalation: Harmful if inhaled. Causes respiratory tract irritation. High vapor concentrations may cause drowsiness. May cause kidney damage. Extreme exposures could result in a build-up of fluid in the lungs (pulmonary edema) that might be fatal in severe cases.
Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow vi ctim to rub eyes or keep eyes closed.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Fire or excessive heat may result in violent rupture of the container due to bulk polymerization.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Use with adequate ventilation. Avoid breathing vapor or mist.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Hexachloropropene none listed none listed none listed

OSHA Vacated PELs: Hexachloropropene: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless to pale yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.244 mm Hg @ 25 deg C
Vapor Density: 8.6 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 209 -210 deg C @ 760 mm Hg
Freezing/Melting Point:-73 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:1.762 g/ml
Molecular Formula:C3Cl6
Molecular Weight:248.75

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Light, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 1888-71-7: UD0175000
LD50/LC50:
CAS# 1888-71-7:
     Inhalation, rat: LC50 = 425 ppm/30M;
.

Carcinogenicity:
CAS# 1888-71-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: Terrestrial: Moderate mobility in soil and is likely to leach. Aquatic: Will absorb to suspended solids and sediment. Atmospheric: Exists solely in the vapor phase with a half-life of 21 days. Slight biodegradation but may be highly bioconcentrated.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 1888-71-7: waste number U243.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: TOXIC LIQUIDS, ORGANIC, N.O.S. TOXIC LIQUID ORGANIC NOS (HEXACHLOROPROPENE)
Hazard Class: 6.1 6.1
UN Number: UN2810 UN2810
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 1888-71-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 1888-71-7: Effective 3/7/87, Sunset 12/19/95
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     CAS# 1888-71-7: Section 5
TSCA Significant New Use Rule
     CAS# 1888-71-7: This product is for research and development use only.      It is subject to a SNUR which has specific requirements and restrictions.      The specific citation for this product is 4040 CFR 721.4155.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 1888-71-7: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 1888-71-7: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 1888-71-7 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T
Risk Phrases:

     R 23 Toxic by inhalation.
     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)

     CAS# 1888-71-7: No information available.
Canada - DSL/NDSL
     CAS# 1888-71-7 is listed on Canada's NDSL List.
Canada - WHMIS
     This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 1888-71-7 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 12/28/1998
Revision #5 Date: 5/16/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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