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MSDS  
:
 Cyclohexane-D12, 99.5 Atom % D
CAS  
:
 1735-17-7
SYNONYMS  
:
 None.

Section 1 - Chemical Product and Company Identification
MSDS Name: Cyclohexane-D12, 99.5 Atom % D
Catalog Numbers: AC166280000, AC166280010, AC166280050
Synonyms:
None.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
1735-17-7 Cyclohexane-D12 99.5 217-077-3

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless liquid. Flash Point: -20 deg C.
Danger! Highly flammable. Causes eye and skin irritation. Causes digestive and respiratory tract irritation. Aspiration hazard if swallowed. Can enter lungs and cause damage. May cause respiratory and digestive tract irritation. May cause eye and skin irritation. May cause central nervous system depression. May cause liver and kidney damage. Hygroscopic (absorbs moisture from the air). The toxicological properties of this material have not been fully investigated.
Target Organs: Kidneys, central nervous system, liver, cardiovascular system.


Potential Health Effects
Eye: May cause mild eye irritation. Causes eye irritation.
Skin: Causes skin irritation. May be absorbed through the skin in harmful amounts. May cause irritation with burning pain, itching and redness. The toxicological properties of this material have not been fully investigated.
Ingestion: Ingestion of large amounts may cause gastrointestinal irritation. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May cause vascular collapse and damage. The toxicological properties of this substance have not been fully investigated. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation. May cause respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema. May be fatal if exposed to high concentrations. May cause pulmonary edema and severe respiratory disturbances. Vapors may cause dizziness or suffocation.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. May cause liver and kidney damage.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow vi ctim to rub eyes or keep eyes closed.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Possible aspiration hazard. Get medical aid immediately. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extremely flammable. Material will readily ignite at room temperature. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Liquid will float and may reignite on the surface of water. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. May polymerize explosively when involved in a fire. Will be easily ignited by heat, sparks or flame. Containers may explode when heated. Containers may explode if exposed to fire.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Water may be ineffective. Water may spread fire. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. If water is the only media available, use in flooding amounts. For large fires, use water spray, fog or alcohol-resistant foam. Do NOT use straight streams of water. For large fires, use water spray, fog or regular foam. For small fires, use dry chemical, carbon dioxide, water spray or regular foam. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: -20 deg C ( -4.00 deg F)
Autoignition Temperature: 245 deg C ( 473.00 deg F)
Explosion Limits, Lower:1.3
Upper: 8.0
NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Do not reuse this container. Avoid breathing dust, mist, or vapor. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Cyclohexane-D12 none listed none listed none listed

OSHA Vacated PELs: Cyclohexane-D12: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear neoprene gloves, apron, and/or clothing. Wear nitrile-latex gloves, apron, and/or clothing. Use polyvinyl alcohol or fluorocarbon rubber (viton) gloves.
Clothing: Wear nitrile-latex gloves, apron, and/or clothing. Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: colorless
Odor: sweetish odor - chloroform-like
pH: Not available.
Vapor Pressure: 95 mm Hg
Vapor Density: 2.90
Evaporation Rate:6.1 (Butyl acetate=1)
Viscosity: 1.02 cP at 63F.
Boiling Point: 80.7 deg C
Freezing/Melting Point:6.5 deg C
Decomposition Temperature:Not available.
Solubility: Practically insoluble in water.
Specific Gravity/Density:0.8 (Water=1)
Molecular Formula:CH2(CH2)4CH2
Molecular Weight:84.084

Section 10 - Stability and Reactivity


Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid: Mechanical shock, incompatible materials, ignition sources, excess heat, exposure to moist air or water, oxidizers.
Incompatibilities with Other Materials: Strong oxidizing agents, nitrogen dioxide.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 1735-17-7 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 1735-17-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: DNA damage; E. coli, 10 umol/L
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Fathead Minnow: LC50 = 117.0 mg/L; 96 Hr.; Static conditionsFish: Bluegill/Sunfish: LC50 = 34.72 mg/L; 96 Hr.; 25 degrees CWater flea Daphnia: EC50 = 400.00 mg/L; 48 Hr.; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 227.00 mg/L; 5, 30 minutes; Microtox test No data available.
Environmental: Atmospheric Fate: Cyclohexane is expected to partition to the atmosphere where it will rapidly react with hydroxyl radicals. TERRESTRIAL FATE: If released on land, cyclohexane will be lost through volatilization and should leach into the ground. Cyclohexane is resistant to biodegradation but may biodegrade slowly in the presence of other hydrocarbons that are themselves degraded. AQUATIC FATE: Volatilization from water (estimated half-life 2 hr in a model river) should be the most important fate process occuring in aquatic systems.
Physical: ATMOSPHERIC FATE: In the atmosphere, cyclohexane will degrade by reaction with photochemically produced hydroxyl radicals (half-life 52 hr). The half-life is much faster under photochemical smog conditions with half-lives as low as 6 hr being reported.
Other: No experimental data are available on the bioconcentration of cyclohexane in aquatic organisms. Using the octanol/water partition coefficient, 3.44, one can estimate a BCF of 242 using a recommended regression equation.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: DOT regulated - small quantity provisions apply (see 49CFR173.4) CYCLOHEXANE
Hazard Class: 3
UN Number: UN1145
Packing Group: II
Additional Info:FLASHPOINT -20 C

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 1735-17-7 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 1735-17-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI F
Risk Phrases:

     R 11 Highly flammable.
     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 16 Keep away from sources of ignition - No smoking.
     S 33 Take precautionary measures against static discharges.
     S 37 Wear suitable gloves.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 9 Keep container in a well-ventilated place.
     S 28A After contact with skin, wash immediately with plenty of water
     .

WGK (Water Danger/Protection)

     CAS# 1735-17-7: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 11/17/1998
Revision #6 Date: 3/15/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
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Cyclohexane-D12, 99.5 Atom % D 1735-17-7
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4-(Phenoxymethyl)aniline 57181-90-5
[4-(Phenoxymethyl)phenyl]methanol 262862-97-5
4-(Phenoxymethyl)benzaldehyde 2683-70-7
4-(3-Bromothien-2-yl)benzoic acid 930111-09-4
Ethyl 1-phenyl-5-propyl-1H-pyrazole-4-carboxylate 116344-12-8
2-Fluoro-5-(trifluoromethyl)benzoic acid 115029-23-7
4-Isopropoxybenzoic acid, 98% 13205-46-4
3-(4-Bromo-1-methyl-1H-pyrazol-5-yl)aniline 573711-38-3
Methyl 2-[(2-thienylcarbonyl)amino]thiophene-3-carboxylate 271778-23-5
Ethyl 3-(4-phenethylpiperazino) propanoate 845885-92-9
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2-Bromo-1-(6-bromopyrid-3-yl)ethanone 136592-20-6
n-Undecylamine, 98% 7307-55-3
(3-Methylisoxazol-5-ylmethyl)amine 154016-55-4
Bis(triphenylphosphine)cobalt(II) chloride 14126-40-0
N-Methyl-(3-methylisoxazol-5-ylmethyl)amine 401647-22-1
[1,2-Bis(diphenylphosphino)ethane]dichlorocobalt(II) 18498-01-6
N-Methyl-4-(phenoxymethyl)benzylamine 941716-90-1
Crotyl palladium(II) chloride dimer 12081-18-4
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4-(2-Bromophenyl)-2-methyl-1,3-thiazole 941717-01-7
Dichlorobis(tricyclohexylphosphine)palladium(II) 29934-17-6
Dichloro(1,10-phenanthroline)palladium(II) 14783-10-9
2-Morpholinopyrimidine-5-carboxylic acid 253315-05-8
Oleic acid 112-80-1
4-Methyl-2-pyrid-4-yl-1,3-thiazole-5-carbonyl chloride hydrochloride 953408-88-3
Gold(III) bromide 10294-28-7
Copper(II)-Ethylenediamine Complex for Viscosity Determination of Cellulose 14552-35-3
Sodium tetrachloroaurate dihydrate 13874-02-7
Sulfuric Acid (Fuming) 8014-95-7Sulfuric acid<-td>
2-Methyl hydrogen pyridine-2,5-dicarboxylate 17874-76-9
4-(9H-Purin-6-yl)morpholine 2846-96-0
5,6-Dimethoxyindolin-2-one 6286-64-2
Tris(triphenylphosphine)rhodium(I) chloride 14694-95-2
5-(tert-Butylsulfonyl)-2-methylpyrimidin-4-amine 175201-85-1
5-(Isopropylsulfonyl)-2-(2-pyridyl)pyrimidin-4-amine 175202-02-5
Tetrabutylammonium iodide 311-28-4
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(5-Pyridin-2-ylthien-2-yl)methylamine 306934-92-9
Orcinol monohydrate 6153-39-5
N1-(4-Methyl-3-nitrophenyl)acetamide 2719-14-4



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