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MSDS  
:
 trans-1,2-Bis(tri-n-butylstannyl)ethylene
CAS  
:
 14275-61-7
SYNONYMS  
:
 None found.

Catalog of Chemical Suppliers, Buyers, Custom Synthesis Companies And Equipment Manufacturers
[ trans-1,2-Bis(tri-n-butylstannyl)ethylene 14275-61-7 ]
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Section 1 - Chemical Product and Company Identification
MSDS Name: trans-1,2-Bis(tri-n-butylstannyl)ethylene
Catalog Numbers: AC388670000, AC388670010, AC388670050
Synonyms:
None found.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
14275-61-7 trans-1,2-Bis(tri-n-butylstannyl)ethylene unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: Not available.
Danger! Toxic if swallowed. Danger of serious damage to health by prolonged exposure through inhalation and if swallowed. Harmful if absorbed through the skin. Causes eye and skin irritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. Harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. Toxic if swallowed.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid immediately. Wash mouth out with water.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Do not breathe dust, mist, or vapor. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Store in a tightly closed container. Store under nitrogen.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
trans-1,2-Bis(tri-n-butylstannyl)ethylene none listed none listed none listed

OSHA Vacated PELs: trans-1,2-Bis(tri-n-butylstannyl)ethylene: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Clear liquid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:C26H56Sn2
Molecular Weight:606.15

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, tin/tin oxides.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 14275-61-7 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 14275-61-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: ORGANOTIN COMPOUND, LIQUID, N.O.S.* ORGANOTIN COMPOUND, LIQUID, N.O.S.*
Hazard Class: 6.1 6.1
UN Number: UN2788 UN2788
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 14275-61-7 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 14275-61-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T N
Risk Phrases:

     R 21 Harmful in contact with skin.
     R 25 Toxic if swallowed.
     R 36/38 Irritating to eyes and skin.
     R 48/23/25 Toxic : danger of serious damage to health by prolonged
     exposure through inhalation and if swallowed.
     R 50/53 Very toxic to aquatic organisms, may cause long-term
     adverse effects in the aquatic environment.

Safety Phrases:

     S 35 This material and its container must be disposed of in a safe w
     ay.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 60 This material and its container must be disposed of as hazardou
     s waste.
     S 61 Avoid release to the environment. Refer to special instructions
     /safety data sheets.

WGK (Water Danger/Protection)

     CAS# 14275-61-7: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of D2B, D1B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 2/10/2006
Revision #1 Date: 7/25/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

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NAMECAS
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Ethyl 2-[3,5-di(trifluoromethyl)anilino]-2-oxoacetate 69065-93-6
Lead(II) sulfate 7446-14-2
Propargylaldehyde diethyl acetal 10160-87-9
4-Hydroxy-7-methyl-3-phenyl-1,2-dihydroquinolin-2-one 83609-87-4
Fumaraldehyde bis(dimethylacetal), 90% 6068-62-8
2-Amino-4,6-Dihydroxy-5-Methylpyrimidine 99% Not available
Tetrahydro-2-(2-propynyloxy)-2H-pyran 6089-04-9
Methyl 2-bromophenylacetate 57486-69-8
N-Carbobenzyloxy-L-valine 1149-26-4
Ethyl 4-(dimethylamino)butanoate 22041-23-2
2-Bromohexane 3377-86-4
Ethyl 3-chlorophenylacetate 14062-29-4
Ethyl 4-chlorophenylacetate 14062-24-9
Calcium bromide dihydrate 22208-73-7
Phenyl acridine-9-carboxylate 109392-90-7
3-(1,3-Benzodioxol-5-yl)propanoic acid 2815-95-4
trans-1,2-Bis(tri-n-butylstannyl)ethylene 14275-61-7
3-Butenyl isothiocyanate 3386-97-8
8-Bromo-7-(3-chloropropyl)-1,3-dimethyl-2,3,6,7-tetrahydro-1H-purine-2,6-dione 98408-17-4
Benzyl(tributyl)phosphonium chloride 1224-56-2
Ethyl 3-amino-4-morpholinobenzoate 71254-75-6
4-(2-Methoxyphenyl)-3-methyl-1H-pyrazole Not available
2-(2-Hydroxyphenyl)succinic acid 73923-83-8
4'-Aminooxanilic acid 103-92-4
6-(4-Chlorophenyl)pyrimidine-2,4-diamine 175137-09-4
10,13-Dimethyl-2,3,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-3,17-dione 63-05-8
4-[(Dimethylamino)methyl]-2,6-dimethylphenol hydrochloride 72920-05-9
Ethyl 2,4-dioxo-3-(2-phenylhydrazono)-4-(2-thienyl)butanoate Not available
(R,R)-(-)-2,3-Dimethoxy-1,4-Bis(Dimethylamino)Butane, 96% 26549-22-4
Magnesium sulfate, anhydrous 7487-88-9
3-(4-Isopropoxyphenyl)acrylic acid Not available
1-(4-Methoxyphenyl)-2-(2-phenyl-5H,6H,7H-imidazo[2,1-b][1,3]thiazol-4-ium-7-yl)ethan-1-one bromide Not available
GUANIDINE CARBONATE, 99% (TITR.) 593-85-1
Potassium thioglycolate, 40-44 wt.% solution in water 34452-51-2
Calcium sulfate hemihydrate 10034-76-1
Sodium perborate monohydrate 10332-33-9
4-Ethoxy-3-methoxybenzaldehyde 120-25-2
Iron(III) bromide 10031-26-2
1-Octadecanesulfonic acid, sodium salt 13893-34-0
1,3-Propanedisulfonic acid, disodium salt 21668-77-9
1,2-Ethanedisulfonic acid dihydrate 5982-56-9
Ammonium thioglycolate, 70 wt.% solution in water 7732-18-5
2-[(2,3-Dibromoallyl)oxy]ethan-1-ol Not available
Magnesium sulfate heptahydrate 10034-99-8
6,6,6-Trichloro-5-hydroxy-2,2-dimethylhexan-3-one 1552-30-3
1-(Trichloromethyl)butyl acetate 80982-62-3
1,1,1-Trichloro-2-propanol 76-00-6



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