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Search   
MSDS  
:
 3-(1H-1,2,4-Triazol-1-ylmethyl)aniline
CAS  
:
 127988-22-1
SYNONYMS  
:
 None Known.

Section 1 - Chemical Product and Company Identification
MSDS Name: 3-(1H-1,2,4-Triazol-1-ylmethyl)aniline
Catalog Numbers: CC45414CB, CC45414DA, CC45414ZZ
Synonyms:
None Known.
Company Identification:
              Maybridge PLC
              Trevillett, Tintagel
              Cornwall, England. PL34 0HW
For information, call:
+44(0)1840770453
For emergencies, call:
+44(0)7702924616

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
127988-22-1 3-(1H-1,2,4-Triazol-1-ylmethyl)aniline 97+% unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: Not available.
Warning! Irritant. Causes eye, skin, and respiratory tract irritation. Harmful if swallowed, inhaled, or absorbed through the skin.
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation. May cause chemical conjunctivitis.
Skin: Causes skin irritation. Harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation: Harmful if inhaled. Causes respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not available
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
3-(1H-1,2,4-Triazol-1-ylmethyl)aniline none listed none listed none listed

OSHA Vacated PELs: 3-(1H-1,2,4-Triazol-1-ylmethyl)aniline: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:85.5 - 86.5 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:C9H10N4
Molecular Weight:174.21

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Acids, acid chlorides, strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information


RTECS#:      
CAS# 127988-22-1 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 127988-22-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1 6.1
UN Number: UN2811 UN2811
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 127988-22-1 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 127988-22-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:

     R 20/21/22 Harmful by inhalation, in contact with skin and if
     swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:

     S 22 Do not breathe dust.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.

WGK (Water Danger/Protection)

     CAS# 127988-22-1: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 12/22/2005
Revision #1 Date: 2/07/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
2,3-Dihydrothieno[3,4-b][1,4]dioxine-5-carboxylic acid 260063-21-6
3-(1H-1,2,4-Triazol-1-ylmethyl)aniline 127988-22-1
N-methyl-N-{4-[(4-methylpiperazin-1-yl)methyl]benzyl}amine 859850-93-4
Methyl 3-(1H-1,2,4-triazol-1-ylmethyl)benzoate 857284-24-3
N-Methyl-p-anisidine, 98% 5961-59-1
Ethyl 5-phenyl-3-isoxazolecarboxylate 7063-99-2
2,3-Dihydrothieno[3,4-b][1,4]dioxine-5-carbaldehyde 204905-77-1
(2-Methyl-2H-indazol-3-yl)methanol 58536-48-4
m-Toluenethiol 108-40-7
Dehydroabietylamine, tech. 1446-61-3
Nitronium hexafluorophosphate 19200-21-6
Dysprosium(III) trifluoromethanesulfonate 139177-62-1
N-Bromophthalimide 2439-85-2
N-(2-Pyridyl)bis(trifluoroethanesulfonimide) 145100-50-1
Bismuth(III) trifluoromethanesulfonate 88189-03-1
1-Heptene 592-76-7
cis-2-Pentene 627-20-3
5-Phthalimido-3-pentyne 339310-24-6
4-Phthalimido-2-butyne 113439-83-1
Trimethyl orthopropionate 24823-81-2
Zirconium atomic absorption standard solution, 1 mg/ml Zr in 5% HF 7440-67-7
DL-Bromosuccinic Acid, 96% 923-06-8
Trimethyl orthobutyrate 43083-12-1
Sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate 79060-88-1
Aluminium trifluoromethanesulfonate 74974-61-1
Cerium(IV) trifluoromethanesulfonate 107792-63-2
Potassium manganate 10294-64-1
Titanium(III) fluoride 13470-08-1
Nitrosonium hexafluorophosphate 16921-91-8
Silver(I) hydrogenfluoride 12249-52-4
3-Oxo-3,4-dihydro-2H-1,4-benzoxazine-6-carboxylic acid 134997-87-8
5-(5-bromo-2-thienyl)-1H-pyrazole 166196-67-4
2-Bromo-1-(3,4-dichlorophenyl)ethan-1-one 2632-10-2
3,4-Dimethoxyphenethyl isothiocyanate 21714-25-0
3-Oxo-3-piperidinopropanenitrile 15029-30-8
N'3-[3-Chloro-5-(trifluoromethyl)-2-pyridyl]-2,5-dichloropyridine-3-carbohydrazide Not available
3-Chloropropiophenone, 98% 936-59-4
5-Methoxy-2-(2,2,2-trifluoroethoxy)benzoic acid 175205-34-2
Ethyl 4-hydroxy-2-[4-(trifluoromethyl)phenyl]-1,3-thiazole-5-carboxylate 227199-08-8
[Hydrazino(methylthio)methylidene](methyl)ammonium iodide Not available
3-(2-Chlorophenyl)-1,1,1-trifluoroacetone 150322-79-5
2-Methyl-1,3-thiazolane-4-carboxylic acid 4165-32-6
2,5-Di(2,2,2-trifluoroethoxy)benzene-1-sulfonyl chloride 152457-95-9
Hexadecyltrimethylammonium chloride, 99% 112-02-7
N1-methyl-2,4-difluoroaniline 138564-16-6
4-(4-Bromo-3-nitrophenyl)-2-methyl-1,3-thiazole hydrobromide Not available
2-Chloro-N-[3,5-di(tert-butyl)phenyl]acetamide Not available
2-(Prop-2-ynyloxy)ethyl acetate 39106-97-3
2-[4-(3-Nitro-2-pyridyl)piperazino]ethan-1-ol 215434-62-1
2-(4-Bromobenzoyl)-1-benzofuran-5-carbaldehyde 186093-87-8



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