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MSDS  
:
 Ammonium chloride, with anti-caking agent
CAS  
:
 124-30-1
SYNONYMS  
:
 None known.

Section 1 - Chemical Product and Company Identification
MSDS Name: Ammonium chloride, with anti-caking agent
Catalog Numbers: AC396400000, AC396400010, AC396400050
Synonyms:
None known.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
12125-02-9 Ammonium chloride 99.5% 235-186-4
124-30-1 n-Octadecylamine <0.04 204-695-3

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white crystalline powder.
Warning! Harmful if swallowed. Causes eye irritation. May cause skin and respiratory tract irritation. Hygroscopic (absorbs moisture from the air).
Target Organs: Kidneys, eyes.


Potential Health Effects
Eye: Causes eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Laboratory experiments have resulted in mutagenic effects. May cause kidney damage.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: Do not induce vomiting. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Ammonium chloride 10 mg/m3 TWA (fume); 20 mg/m3 STEL (fume) 10 mg/m3 TWA (fume) none listed
n-Octadecylamine none listed none listed none listed

OSHA Vacated PELs: Ammonium chloride: 10 mg/m3 TWA n-Octadecylamine: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Crystalline powder
Appearance: white
Odor: Not available.
pH: 4.5 - 5.5 (5% aq.sol.(20C))
Vapor Pressure: 1.3mbar @160 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:340 deg C(subl)
Decomposition Temperature:Not available.
Solubility: 370 mg/L (20C)
Specific Gravity/Density:1.520
Molecular Formula:H4ClN
Molecular Weight:53.49

Section 10 - Stability and Reactivity


Chemical Stability: Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid: Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, acids, bases, bromine trifluoride, nitrates, potassium chlorates, silver salts, carbonates, bromine pentafluoride, lead salts.
Hazardous Decomposition Products: Ammonia and hydrochloric acid fumes.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 12125-02-9: BP4550000; BP4570000      
CAS# 124-30-1: RG4150000
LD50/LC50:
CAS# 12125-02-9:
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, eye: 100 mg Severe;
     Oral, mouse: LD50 = 1300 mg/kg;
     Oral, rat: LD50 = 1650 mg/kg;
.

CAS# 124-30-1:
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Oral, mouse: LD50 = 3 gm/kg;
     Oral, rat: LD50 = 2395 mg/kg;
.

Carcinogenicity:
CAS# 12125-02-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 124-30-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated. Not regulated.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 12125-02-9 is listed on the TSCA inventory.
     CAS# 124-30-1 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 12125-02-9: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 12125-02-9: immediate, delayed.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 12125-02-9 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 12125-02-9 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 124-30-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN
Risk Phrases:

     R 22 Harmful if swallowed.
     R 36 Irritating to eyes.

Safety Phrases:

     S 22 Do not breathe dust.

WGK (Water Danger/Protection)

     CAS# 12125-02-9: 1
     CAS# 124-30-1: 2
Canada - DSL/NDSL
     CAS# 12125-02-9 is listed on Canada's DSL List.
     CAS# 124-30-1 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 12125-02-9 is listed on the Canadian Ingredient Disclosure List.
     CAS# 124-30-1 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 8/30/2007
Revision #1 Date: 3/10/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
3-[(2-Chloroacetyl)amino]thiophene-2-carboxylic acid 648858-95-1
Ammonium chloride, with anti-caking agent 124-30-1
3-Methyladamantane-1-carboxylic acid 33649-73-9
N-[2-Methyl-5-(piperidinosulfonyl)-3-furyl]-N'-phenylurea na
Tetrahydrothiophen-3-one oxime 24030-02-2
N-Phenethylthieno[3,2-d]pyrimidin-4-amine na
2-{4-[3-Chloro-5-(trifluoromethyl)-2-pyridyl]piperazino}ethan-1-ol 215434-40-5
Pentafluorophenyl 4-morpholinobenzoate 921938-51-4
2-Isocyanato-5-methylthiophene 76536-99-7
3-Phenylisoxazole-5-carbonyl chloride 124953-60-2
2-Chloro-1,3-thiazole-5-carbaldehyde 95453-58-0
4-Methyl-2-pyrid-4-yl-1,3-thiazole-5-carbaldehyde 892502-19-1
N-Methyl-(3-phenylisoxazol-5-yl)methylamine 852431-00-6
6-(Tetrahydropyran-4-yloxy)nicotinaldehyde 910036-95-2
Lithium sulfide, powder 12136-58-2
Citrus Burst? 3 Not available
Citrus Burst? 2 Not available
2-Hydroxyphenylboronic acid 89466-08-0
2-(Methylthio)phenylboronic acid 168618-42-6
N-(3-Chlorophenyl)-N'-[6-chloro-4-(trifluoromethyl)-2-pyridyl]urea na
3,5-Dichlorophenyl isothiocyanate 6590-93-8
1,5-Di(3-bromopropanoyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one na
Quinine, anhydrous, 99% (titr) 130-95-0
4-(4-Chloro-3-nitrophenyl)-2-(4-fluorophenyl)-1,3-thiazole na
1-(tert-Butoxycarbonyl)piperidine-3-carboxylic acid 84358-12-3
1-(4-Bromobenzyl)piperazine 91345-62-9
Potassium Phosphate, Dibasic Trihydrate, 99+% 16788-57-1
1-Allylpiperazine 13961-36-9
1-(2-Aminoethyl)-4-methylpiperazine 934-98-5
1-[(2-Ethyl-4-methyl-1H-imidazol-5-yl)methyl]-4-[5-(trifluoromethyl)-2-pyridinyl]piperazine na
1,2,3,4,6,7-Hexabromonaphthalene na
N-[3-(4-Chloroanilino)-1H-1,2,4-triazol-5-yl]-N'-isopropylurea na
N-[3-(4-Chloroanilino)-1H-1,2,4-triazol-5-yl]-N'-propylurea na
2-Phenylpyrrolidine 1006-64-0
Methyl 2,3-diaminobenzoate 107582-20-7
Benzyl Methyl Sulfide, 98% 766-92-7
5-Bromopicolinic acid 30766-11-1
2-Methoxy-4-vinylphenol 7786-61-0
1-(Thien-2-ylmethyl)piperidine-4-carboxylic acid hydrochloride hydrate 944450-84-4
Phenyltrifluorosilane 368-47-8
2-Bromo-1-(1-methyl-1H-benzimidazol-5-yl)ethanone hydrobromide 944450-78-6
2-Fluoro-4-picoline 461-87-0
N-Methyl-[(4-bromothien-3-yl)methyl]amine hydrochloride 944450-82-2
2-[1-Methyl-3-(trifluoromethyl)-1H-pyrazol-5-yl]benzylamine 910095-35-1
2,5-Bis(trifluoromethyl)benzaldehyde 395-64-2
(4-Thien-2-yltetrahydropyran-4-yl)methylamine 906422-74-0
3-Hydroxy-5-[2-(trifluoromethyl)anilino]isothiazole-4-carbonitrile na
5-Nitro-2-furaldehyde, 99% 698-63-5
Ethyl 2,3-dibromo-3-phenylpropanoate 5464-70-0
1-(3-Chloro-4-hydroxyphenyl)propan-1-one 2892-27-5



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