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Section 1 - Chemical Product and Company Identification |
MSDS Name: Diallylamine, 97%
Catalog Numbers:
AC112040000, AC112040010, AC112040050, AC112042500
Synonyms:
Di-2-propenylamine; N-2-Propenyl-2-propen-1-amine.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 124-02-7 |
Diallylamine |
97 | 204-671-2 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless to light yellow liquid. Flash Point: 7 deg C.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns. Harmful if absorbed through
the skin. Flammable liquid and vapor.
May be harmful if swallowed or inhaled.
Target Organs: Kidneys, liver, eyes, skin,
mucous membranes.
Potential Health Effects
Eye:
Lachrymator (substance which increases the flow of tears). Causes
severe eye irritation and possible burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns. Amines have
been known to cause skin irritation/corrosion and allergic skin
reaction.
Ingestion:
Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract. May be harmful if
inhaled. Vapors may cause dizziness or suffocation.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and
flash back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Water may be ineffective. Material
is lighter than water and a fire may be spread by the use of water.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Will be
easily ignited by heat, sparks or flame. Containers may explode if
exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Water may be ineffective.
Water may spread fire. If water is the only media available, use in
flooding amounts. For large fires, use water spray, fog or
alcohol-resistant foam. Do NOT use straight streams of water.
Flash Point: 7 deg C ( 44.60 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 0
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Do not get in eyes, on skin,
or on clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep away from heat, sparks and
flame. Do not ingest or inhale. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Diallylamine
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Diallylamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: 3.35 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 111-112 deg C @ 760 mm Hg
Freezing/Melting Point:-88 deg C
Decomposition Temperature:Not available.
Solubility: 90 g/l (20癈)
Specific Gravity/Density:.7890 g/ml
Molecular Formula:C6H11N
Molecular Weight:97.16
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, carbon dioxide, acid anhydrides, acid
chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 124-02-7:
UC6650000
LD50/LC50:
CAS# 124-02-7:
Inhalation, rat:
LC50 = 795 ppm/8H;
Oral, mouse:
LD50 = 355 mg/kg;
Oral, rat: LD50
= 578 mg/kg;
Skin, rabbit: LD50 =
280 uL/kg;
.
Dermal LD50, rabbit: 280 uL/kg = 221 mg/kg.
Carcinogenicity:
CAS# 124-02-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
DIALLYLAMINE |
DIALLYLAMINE |
| Hazard Class: |
3 |
3 |
| UN Number: |
UN2359 |
UN2359 |
| Packing Group: |
II |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 124-02-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 124-02-7 can be found on the
following state right to know lists: New Jersey.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T F
Risk Phrases:
R 11 Highly flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 24 Toxic in contact with skin.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
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WGK (Water Danger/Protection)
CAS# 124-02-7: No information available.
Canada - DSL/NDSL
CAS# 124-02-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, E, D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 10/24/1998
Revision #5 Date: 9/14/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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