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MSDS  
:
 Sodium perborate monohydrate
CAS  
:
 10332-33-9
SYNONYMS  
:
 None Known.

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[ Sodium perborate monohydrate 10332-33-9 ]
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Section 1 - Chemical Product and Company Identification
MSDS Name: Sodium perborate monohydrate
Catalog Numbers: AC386410000, AC386410010, AC386410250, AC386412500
Synonyms:
None Known.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
10332-33-9 Sodium perborate monohydrate unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white powder.
Danger! Strong oxidizer. Contact with other material may cause a fire. May cause severe eye, skin and respiratory tract irritation with possible burns. Harmful if swallowed. Causes eye and skin irritation. May cause respiratory tract irritation.
Target Organs: Eyes, skin.


Potential Health Effects
Eye: Causes eye irritation. May cause permanent corneal opacification.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Effects may be delayed.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Contact professional fire-fighters immediately.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 1; Special Hazard: OX

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid breathing dust, mist, or vapor. Avoid contact with skin and eyes. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container. Store below 40癈.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Sodium perborate none listed none listed none listed
Sodium perborate monohydrate none listed none listed none listed

OSHA Vacated PELs: Sodium perborate: No OSHA Vacated PELs are listed for this chemical. Sodium perborate monohydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Powder
Appearance: white
Odor: odorless
pH: 10 (1.5% aq. solution)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:60 deg C
Solubility: 15 g/l (20癈)
Specific Gravity/Density:Not available.
Molecular Formula:BNaO3.H2O
Molecular Weight:99.81

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid: Incompatible materials, ignition sources, dust generation, excess heat, combustible materials, exposure to moist air or water, temperatures above 55癈.
Incompatibilities with Other Materials: Combustible and flammable materials (e.g. alkyl resins, asphalt, gasoline, grease, methyl acetone, polystyrene, polyurethane), reducing agents.
Hazardous Decomposition Products: Oxygen.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7632-04-4: SC7310000      
CAS# 10332-33-9: SC7320000
LD50/LC50:
CAS# 7632-04-4:
     Oral, mouse: LD50 = 3250 mg/kg;
.

CAS# 10332-33-9:
     Draize test, rabbit, eye: 6.3 mg Mild;
.

Carcinogenicity:
CAS# 7632-04-4: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10332-33-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: SODIUM PERBORATE MONOHYDRATE SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1 5.1
UN Number: UN3377 UN3377
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7632-04-4 is listed on the TSCA inventory.
     CAS# 10332-33-9 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7632-04-4 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 10332-33-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN O
Risk Phrases:

     R 22 Harmful if swallowed.
     R 36/38 Irritating to eyes and skin.
     R 8 Contact with combustible material may cause fire.

Safety Phrases:

     S 17 Keep away from combustible material.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)

     CAS# 7632-04-4: 1
     CAS# 10332-33-9: No information available.
Canada - DSL/NDSL
     CAS# 7632-04-4 is listed on Canada's DSL List.
     CAS# 10332-33-9 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C, D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 2/10/2006
Revision #2 Date: 12/14/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Dimethyl (1-hydroxy-1-methylethyl)phosphonate 10184-68-6
3-(4-Methoxyphenyl)-1-(2-methyloxiran-2-yl)prop-2-en-1-one 29808-43-3
N1-(4-Fluorophenyl)-2-aminobenzamide Not available
Ethyl 2-[3,5-di(trifluoromethyl)anilino]-2-oxoacetate 69065-93-6
Lead(II) sulfate 7446-14-2
Propargylaldehyde diethyl acetal 10160-87-9
4-Hydroxy-7-methyl-3-phenyl-1,2-dihydroquinolin-2-one 83609-87-4
Fumaraldehyde bis(dimethylacetal), 90% 6068-62-8
2-Amino-4,6-Dihydroxy-5-Methylpyrimidine 99% Not available
Tetrahydro-2-(2-propynyloxy)-2H-pyran 6089-04-9
Methyl 2-bromophenylacetate 57486-69-8
N-Carbobenzyloxy-L-valine 1149-26-4
Ethyl 4-(dimethylamino)butanoate 22041-23-2
2-Bromohexane 3377-86-4
Ethyl 3-chlorophenylacetate 14062-29-4
Ethyl 4-chlorophenylacetate 14062-24-9
Calcium bromide dihydrate 22208-73-7
Phenyl acridine-9-carboxylate 109392-90-7
3-(1,3-Benzodioxol-5-yl)propanoic acid 2815-95-4
trans-1,2-Bis(tri-n-butylstannyl)ethylene 14275-61-7
3-Butenyl isothiocyanate 3386-97-8
8-Bromo-7-(3-chloropropyl)-1,3-dimethyl-2,3,6,7-tetrahydro-1H-purine-2,6-dione 98408-17-4
Benzyl(tributyl)phosphonium chloride 1224-56-2
Ethyl 3-amino-4-morpholinobenzoate 71254-75-6
4-(2-Methoxyphenyl)-3-methyl-1H-pyrazole Not available
2-(2-Hydroxyphenyl)succinic acid 73923-83-8
4'-Aminooxanilic acid 103-92-4
6-(4-Chlorophenyl)pyrimidine-2,4-diamine 175137-09-4
10,13-Dimethyl-2,3,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-3,17-dione 63-05-8
4-[(Dimethylamino)methyl]-2,6-dimethylphenol hydrochloride 72920-05-9
Ethyl 2,4-dioxo-3-(2-phenylhydrazono)-4-(2-thienyl)butanoate Not available
(R,R)-(-)-2,3-Dimethoxy-1,4-Bis(Dimethylamino)Butane, 96% 26549-22-4
Magnesium sulfate, anhydrous 7487-88-9
3-(4-Isopropoxyphenyl)acrylic acid Not available
1-(4-Methoxyphenyl)-2-(2-phenyl-5H,6H,7H-imidazo[2,1-b][1,3]thiazol-4-ium-7-yl)ethan-1-one bromide Not available
GUANIDINE CARBONATE, 99% (TITR.) 593-85-1
Potassium thioglycolate, 40-44 wt.% solution in water 34452-51-2
Calcium sulfate hemihydrate 10034-76-1
Sodium perborate monohydrate 10332-33-9
4-Ethoxy-3-methoxybenzaldehyde 120-25-2
Iron(III) bromide 10031-26-2
1-Octadecanesulfonic acid, sodium salt 13893-34-0
1,3-Propanedisulfonic acid, disodium salt 21668-77-9
1,2-Ethanedisulfonic acid dihydrate 5982-56-9
Ammonium thioglycolate, 70 wt.% solution in water 7732-18-5
2-[(2,3-Dibromoallyl)oxy]ethan-1-ol Not available
Magnesium sulfate heptahydrate 10034-99-8
6,6,6-Trichloro-5-hydroxy-2,2-dimethylhexan-3-one 1552-30-3
1-(Trichloromethyl)butyl acetate 80982-62-3
1,1,1-Trichloro-2-propanol 76-00-6



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