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Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium perborate monohydrate
Catalog Numbers:
AC386410000, AC386410010, AC386410250, AC386412500
Synonyms:
None Known.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 10332-33-9 |
Sodium perborate monohydrate |
| unlisted |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white powder.
Danger! Strong oxidizer. Contact with other
material may cause a fire. May cause severe eye, skin and
respiratory tract irritation with possible burns. Harmful if
swallowed. Causes eye and skin irritation. May cause respiratory
tract irritation.
Target Organs: Eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause permanent corneal opacification.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Effects may be delayed.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May accelerate burning if involved in a
fire. Containers may explode when heated.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Contact professional fire-fighters immediately.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 1; Special Hazard: OX
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not use
combustible materials such as paper towels to clean up spill. Do not
let this chemical enter the environment.
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Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, mist, or vapor. Avoid contact
with skin and eyes. Keep container tightly closed. Avoid contact with
clothing and other combustible materials. Avoid ingestion and
inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Store below 40癈.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Sodium perborate
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none listed
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none listed
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none listed
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| Sodium perborate monohydrate
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none listed
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none listed
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none listed
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OSHA Vacated PELs:
Sodium perborate:
No OSHA Vacated PELs are listed for this chemical.
Sodium perborate monohydrate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Powder
Appearance: white
Odor: odorless
pH: 10 (1.5% aq. solution)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:60 deg C
Solubility: 15 g/l (20癈)
Specific Gravity/Density:Not available.
Molecular Formula:BNaO3.H2O
Molecular Weight:99.81
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Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures. Hygroscopic: absorbs
moisture or water from the air.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, combustible materials, exposure to moist air or water,
temperatures above 55癈.
Incompatibilities with Other Materials:
Combustible and flammable materials (e.g. alkyl resins, asphalt,
gasoline, grease, methyl acetone, polystyrene, polyurethane),
reducing agents.
Hazardous Decomposition Products:
Oxygen.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 7632-04-4:
SC7310000
CAS# 10332-33-9:
SC7320000
LD50/LC50:
CAS# 7632-04-4: Oral, mouse: LD50
= 3250 mg/kg; .
CAS# 10332-33-9: Draize test,
rabbit, eye: 6.3 mg Mild; .
Carcinogenicity:
CAS# 7632-04-4:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10332-33-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
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Section 12 - Ecological Information
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No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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US DOT |
Canada TDG |
| Shipping Name: |
SODIUM PERBORATE MONOHYDRATE |
SODIUM PERBORATE MONOHYDRATE |
| Hazard Class: |
5.1 |
5.1 |
| UN Number: |
UN3377 |
UN3377 |
| Packing Group: |
III |
III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7632-04-4 is listed on the TSCA inventory.
CAS# 10332-33-9 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7632-04-4 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 10332-33-9 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 8 Contact with combustible material may cause fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7632-04-4: 1
CAS# 10332-33-9: No information available.
Canada - DSL/NDSL
CAS# 7632-04-4 is listed on Canada's DSL List.
CAS# 10332-33-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
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Section 16 - Additional Information
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MSDS Creation Date: 2/10/2006 Revision #2 Date: 12/14/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
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