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MSDS  
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 Calcium sulfate hemihydrate
CAS  
:
 10034-76-1
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[ Calcium sulfate hemihydrate 10034-76-1 ]
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Section 1 - Chemical Product and Company Identification
MSDS Name: Calcium sulfate hemihydrate
Catalog Numbers: AC385350000
Synonyms:

Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
10034-76-1 Calcium sulfate hemihydrate unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Not available. Appearance: white solid.
Not available.
Target Organs: None known.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Not available.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: Substance is noncombustible.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Calcium sulfate 10 mg/m3 TWA (particulate matter containing no asbestos and < 1% crystalline sil ica) 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)
Calcium sulfate hemihydrate none listed none listed none listed

OSHA Vacated PELs: Calcium sulfate: 15 mg/m3 TWA; 5 mg/m3 TWA (respirable fraction) Calcium sulfate hemihydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: 0.8 g/l (20癈)
Specific Gravity/Density:Not available.
Molecular Formula:CaSO4.0.5H2O
Molecular Weight:145.15

Section 10 - Stability and Reactivity


Chemical Stability: Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid: Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Oxides of sulfur, calcium oxide.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information


RTECS#:      
CAS# 7778-18-9: WS6920000      
CAS# 10034-76-1 unlisted.
LD50/LC50:
Not available.
Not available.

Carcinogenicity:
CAS# 7778-18-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10034-76-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7778-18-9 is listed on the TSCA inventory.
     CAS# 10034-76-1 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7778-18-9 can be found on the following state right to know lists: Pennsylvania, Minnesota, Massachusetts.
     CAS# 10034-76-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:


Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

     CAS# 7778-18-9: 0
     CAS# 10034-76-1: 0
Canada - DSL/NDSL
     CAS# 7778-18-9 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 2/10/2006
Revision #0 Date: Original.

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.

ALL Chemical Analysis PAGES IN THIS GROUP
NAMECAS
Dimethyl (1-hydroxy-1-methylethyl)phosphonate 10184-68-6
3-(4-Methoxyphenyl)-1-(2-methyloxiran-2-yl)prop-2-en-1-one 29808-43-3
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Ethyl 2-[3,5-di(trifluoromethyl)anilino]-2-oxoacetate 69065-93-6
Lead(II) sulfate 7446-14-2
Propargylaldehyde diethyl acetal 10160-87-9
4-Hydroxy-7-methyl-3-phenyl-1,2-dihydroquinolin-2-one 83609-87-4
Fumaraldehyde bis(dimethylacetal), 90% 6068-62-8
2-Amino-4,6-Dihydroxy-5-Methylpyrimidine 99% Not available
Tetrahydro-2-(2-propynyloxy)-2H-pyran 6089-04-9
Methyl 2-bromophenylacetate 57486-69-8
N-Carbobenzyloxy-L-valine 1149-26-4
Ethyl 4-(dimethylamino)butanoate 22041-23-2
2-Bromohexane 3377-86-4
Ethyl 3-chlorophenylacetate 14062-29-4
Ethyl 4-chlorophenylacetate 14062-24-9
Calcium bromide dihydrate 22208-73-7
Phenyl acridine-9-carboxylate 109392-90-7
3-(1,3-Benzodioxol-5-yl)propanoic acid 2815-95-4
trans-1,2-Bis(tri-n-butylstannyl)ethylene 14275-61-7
3-Butenyl isothiocyanate 3386-97-8
8-Bromo-7-(3-chloropropyl)-1,3-dimethyl-2,3,6,7-tetrahydro-1H-purine-2,6-dione 98408-17-4
Benzyl(tributyl)phosphonium chloride 1224-56-2
Ethyl 3-amino-4-morpholinobenzoate 71254-75-6
4-(2-Methoxyphenyl)-3-methyl-1H-pyrazole Not available
2-(2-Hydroxyphenyl)succinic acid 73923-83-8
4'-Aminooxanilic acid 103-92-4
6-(4-Chlorophenyl)pyrimidine-2,4-diamine 175137-09-4
10,13-Dimethyl-2,3,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-3,17-dione 63-05-8
4-[(Dimethylamino)methyl]-2,6-dimethylphenol hydrochloride 72920-05-9
Ethyl 2,4-dioxo-3-(2-phenylhydrazono)-4-(2-thienyl)butanoate Not available
(R,R)-(-)-2,3-Dimethoxy-1,4-Bis(Dimethylamino)Butane, 96% 26549-22-4
Magnesium sulfate, anhydrous 7487-88-9
3-(4-Isopropoxyphenyl)acrylic acid Not available
1-(4-Methoxyphenyl)-2-(2-phenyl-5H,6H,7H-imidazo[2,1-b][1,3]thiazol-4-ium-7-yl)ethan-1-one bromide Not available
GUANIDINE CARBONATE, 99% (TITR.) 593-85-1
Potassium thioglycolate, 40-44 wt.% solution in water 34452-51-2
Calcium sulfate hemihydrate 10034-76-1
Sodium perborate monohydrate 10332-33-9
4-Ethoxy-3-methoxybenzaldehyde 120-25-2
Iron(III) bromide 10031-26-2
1-Octadecanesulfonic acid, sodium salt 13893-34-0
1,3-Propanedisulfonic acid, disodium salt 21668-77-9
1,2-Ethanedisulfonic acid dihydrate 5982-56-9
Ammonium thioglycolate, 70 wt.% solution in water 7732-18-5
2-[(2,3-Dibromoallyl)oxy]ethan-1-ol Not available
Magnesium sulfate heptahydrate 10034-99-8
6,6,6-Trichloro-5-hydroxy-2,2-dimethylhexan-3-one 1552-30-3
1-(Trichloromethyl)butyl acetate 80982-62-3
1,1,1-Trichloro-2-propanol 76-00-6



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